A new tricyclic triketone from tandem condensation reactions

  • I. David Reingold
  • , Anna M. Butterfield
  • , Bevin C. Daglen
  • , Robert S. Walters
  • , Kathryn Allen
  • , Susan Scheuring
  • , Katrina Kratz
  • , Milan Gembický
  • , Peter Baran

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

Perhydrophenanthrene-1,5,10-trione (6) was isolated from the reaction of methyl 3-(carboxymethyl)cyclohexanone and cyclohexenone in a tandem Michael-Claisen reaction. NMR and X-ray analysis confirmed the structure of the product.

Original languageEnglish
Pages (from-to)3835-3837
Number of pages3
JournalTetrahedron Letters
Volume46
Issue number22
DOIs
StatePublished - 30 May 2005

Keywords

  • Claisen
  • Kekulene
  • Michael
  • Modeling
  • Perhydrophenanthrene
  • Tandem condensations
  • Tricyclic
  • Triketone

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