Abstract
A new peridynamic (PD) model for crevice corrosion damage is introduced and cross-validated with experimental results from the literature. Electrochemical mechanisms are reduced to a simple metal-ion concentration-dependent corrosion rate. Computations over domains with extreme aspect ratios like those seen in crevices are efficiently performed by modifying the PD formulation to accommodate arbitrary-shape horizons. The model is validated against experimental results on bolted washers. Simulations predict both the location and the depth of deep corrosion trenches that form at a distance from the crevice mouth. Far-field boundary conditions are used to autonomously reproduce the experimentally observed progression of crevice corrosion. The PD model results also show that the two factors considered here (diffusion-driven transport of dissolved metal ions, and dissolution being dependent on their concentration) are sufficient to predict the evolution of crevice corrosion.
| Original language | English |
|---|---|
| Article number | 139512 |
| Journal | Electrochimica Acta |
| Volume | 401 |
| DOIs | |
| State | Published - Jan 2022 |
| Externally published | Yes |
Keywords
- Corrosion
- Crevice corrosion
- Modeling
- Nickel alloy
- Nonlocal mass transfer
- Peridynamics