TY - JOUR
T1 - Alkaloid Variation in New Zealand Kōwhai, Sophora Species
AU - McDougal, Owen M.
AU - Heenan, Peter B.
AU - Jaksons, Peter
AU - Sansom, Catherine E.
AU - Smallfield, Bruce M.
AU - Perry, Nigel B.
AU - van Klink, John W.
N1 - McDougal, Owen M.; Heenan, Peter B.; Jaksons, Peter; Sansom, Catherine E.; Smallfield, Bruce M.; Perry, Nigel B.; and van Klink, John W. (2015). "Alkaloid Variation in New Zealand Kōwhai, Sophora Species". Phytochemistry, 118, 9-16. http://dx.doi.org/10.1016/j.phytochem.2015.07.019
PY - 2015/10/1
Y1 - 2015/10/1
N2 - Alkaloid contents of leaf and seed samples of eight species of Sophora native to New Zealand, plus Sophora cassioides from Chile are reported. Fifty-six leaf and forty-two seed samples were analysed for alkaloid content by proton nuclear magnetic resonance spectroscopy, which showed major alkaloids as cytisine, N -methyl cytisine and matrine. GC analyses quantified these and identified further alkaloid components. The alkaloids identified were cytisine, sparteine, and matrine-types common to Sophora from other regions of the world. Cytisine, N -methyl cytisine, and matrine were generally the most abundant alkaloids across all species with seeds containing the highest concentrations of alkaloids. However, there was no clear taxonomic grouping based on alkaloid composition. A quantitative analysis of various parts of two Sophora microphylla trees showed that the seeds were the richest source of alkaloids (total 0.4–0.5% DM), followed by leaf and twig (0.1–0.3%) and then bark (0.04–0.06%), with only low amounts (Sophora species to date and presents data for three species of Sophora for which no prior chemistry has been reported.
AB - Alkaloid contents of leaf and seed samples of eight species of Sophora native to New Zealand, plus Sophora cassioides from Chile are reported. Fifty-six leaf and forty-two seed samples were analysed for alkaloid content by proton nuclear magnetic resonance spectroscopy, which showed major alkaloids as cytisine, N -methyl cytisine and matrine. GC analyses quantified these and identified further alkaloid components. The alkaloids identified were cytisine, sparteine, and matrine-types common to Sophora from other regions of the world. Cytisine, N -methyl cytisine, and matrine were generally the most abundant alkaloids across all species with seeds containing the highest concentrations of alkaloids. However, there was no clear taxonomic grouping based on alkaloid composition. A quantitative analysis of various parts of two Sophora microphylla trees showed that the seeds were the richest source of alkaloids (total 0.4–0.5% DM), followed by leaf and twig (0.1–0.3%) and then bark (0.04–0.06%), with only low amounts (Sophora species to date and presents data for three species of Sophora for which no prior chemistry has been reported.
KW - Fabaceae
KW - Sophora chathamica
KW - Sophora fulvida
KW - Sophora godleyi
KW - Sophora longicarinata
KW - Sophora microphylla
UR - https://scholarworks.boisestate.edu/chem_facpubs/100
UR - http://dx.doi.org/10.1016/j.phytochem.2015.07.019
U2 - 10.1016/j.phytochem.2015.07.019
DO - 10.1016/j.phytochem.2015.07.019
M3 - Article
C2 - 26253652
JO - Phytochemistry
JF - Phytochemistry
ER -