Coordination of a tethered epoxide to a coordinatively unsaturated rhenium oxo complex

Kevin P. Gable; Eric C. Brown

doi:10.1021/om030278a

Coordination of a tethered epoxide to a coordinatively unsaturated rhenium oxo complex

Kevin P. Gable
, Eric C. Brown

Chemistry Department

Oregon State University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The characterization of a tethered epoxide associated with a coordinatively unsaturated rhenium oxo complex was investigated. The rhenium complex prepared via a multistep route was studied for reductive deoxygenation with PPh₃. The deoxygenation resulted in a species whose nuclear magnetic resonance (NMR) based characteristics were consistent with expectation for a rhenium(V)-epoxide complex.

Original language	English
Pages (from-to)	3096-3101
Number of pages	6
Journal	Organometallics
Volume	22
Issue number	15
DOIs	https://doi.org/10.1021/om030278a
State	Published - 21 Jul 2003

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title = "Coordination of a tethered epoxide to a coordinatively unsaturated rhenium oxo complex",

abstract = "The characterization of a tethered epoxide associated with a coordinatively unsaturated rhenium oxo complex was investigated. The rhenium complex prepared via a multistep route was studied for reductive deoxygenation with PPh3. The deoxygenation resulted in a species whose nuclear magnetic resonance (NMR) based characteristics were consistent with expectation for a rhenium(V)-epoxide complex.",

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T1 - Coordination of a tethered epoxide to a coordinatively unsaturated rhenium oxo complex

AU - Gable, Kevin P.

AU - Brown, Eric C.

PY - 2003/7/21

Y1 - 2003/7/21

N2 - The characterization of a tethered epoxide associated with a coordinatively unsaturated rhenium oxo complex was investigated. The rhenium complex prepared via a multistep route was studied for reductive deoxygenation with PPh3. The deoxygenation resulted in a species whose nuclear magnetic resonance (NMR) based characteristics were consistent with expectation for a rhenium(V)-epoxide complex.

AB - The characterization of a tethered epoxide associated with a coordinatively unsaturated rhenium oxo complex was investigated. The rhenium complex prepared via a multistep route was studied for reductive deoxygenation with PPh3. The deoxygenation resulted in a species whose nuclear magnetic resonance (NMR) based characteristics were consistent with expectation for a rhenium(V)-epoxide complex.

UR - https://www.scopus.com/pages/publications/0041340615

U2 - 10.1021/om030278a

DO - 10.1021/om030278a

M3 - Article

AN - SCOPUS:0041340615

SN - 0276-7333

VL - 22

SP - 3096

EP - 3101

JO - Organometallics

JF - Organometallics

IS - 15

ER -

Coordination of a tethered epoxide to a coordinatively unsaturated rhenium oxo complex

Abstract

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