Electrogenerated poly(chiral dicarbazole) films for the reagentless grafting of enzymes

Serge Cosnier; Robert S. Marks; Jean Paul Lellouche; Karine Perie; Daniel Fologea; Sabine Szunerits

doi:10.1002/1521-4109(200010)12:14<1107::AID-ELAN1107>3.0.CO;2-8

Electrogenerated poly(chiral dicarbazole) films for the reagentless grafting of enzymes

Serge Cosnier, Robert S. Marks, Jean Paul Lellouche, Karine Perie, Daniel Fologea, Sabine Szunerits

Physics Department

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

New chiral dicarbazole derivatives functionalized by N-hydroxysuccinimide and pentafluorophenoxy groups have been synthesized and electrochemically characterized. Upon oxidative electropolymerization of these monomers in organic electrolytes electroactive poly(dicarbazole) films were formed on platimim electrodes. The subsequent chemical grafting of glucose oxidase on the poly(dicarbazole) films was easily performed by immersion in an enzymatic aqueous solution. The amperometric response of the resulting biosensors to glucose has been studied at 0.6 V vs. aqueous saturated calomel electrode.

Original language	English
Pages (from-to)	1107-1112
Number of pages	6
Journal	Electroanalysis
Volume	12
Issue number	14
DOIs	https://doi.org/10.1002/1521-4109(200010)12:14<1107::AID-ELAN1107>3.0.CO;2-8
State	Published - 2000

Keywords

Biosensor
Carbazole
Chiral polymer
Electropolymerization
Glucose oxidase

Access to Document

10.1002/1521-4109(200010)12:14<1107::AID-ELAN1107>3.0.CO;2-8

Cite this

@article{c4f63ac9e7b04d27bbe865cec4948ebe,

title = "Electrogenerated poly(chiral dicarbazole) films for the reagentless grafting of enzymes",

abstract = "New chiral dicarbazole derivatives functionalized by N-hydroxysuccinimide and pentafluorophenoxy groups have been synthesized and electrochemically characterized. Upon oxidative electropolymerization of these monomers in organic electrolytes electroactive poly(dicarbazole) films were formed on platimim electrodes. The subsequent chemical grafting of glucose oxidase on the poly(dicarbazole) films was easily performed by immersion in an enzymatic aqueous solution. The amperometric response of the resulting biosensors to glucose has been studied at 0.6 V vs. aqueous saturated calomel electrode.",

keywords = "Biosensor, Carbazole, Chiral polymer, Electropolymerization, Glucose oxidase",

author = "Serge Cosnier and Marks, {Robert S.} and Lellouche, {Jean Paul} and Karine Perie and Daniel Fologea and Sabine Szunerits",

year = "2000",

doi = "10.1002/1521-4109(200010)12:14<1107::AID-ELAN1107>3.0.CO;2-8",

language = "English",

volume = "12",

pages = "1107--1112",

number = "14",

}

TY - JOUR

T1 - Electrogenerated poly(chiral dicarbazole) films for the reagentless grafting of enzymes

AU - Cosnier, Serge

AU - Marks, Robert S.

AU - Lellouche, Jean Paul

AU - Perie, Karine

AU - Fologea, Daniel

AU - Szunerits, Sabine

PY - 2000

Y1 - 2000

N2 - New chiral dicarbazole derivatives functionalized by N-hydroxysuccinimide and pentafluorophenoxy groups have been synthesized and electrochemically characterized. Upon oxidative electropolymerization of these monomers in organic electrolytes electroactive poly(dicarbazole) films were formed on platimim electrodes. The subsequent chemical grafting of glucose oxidase on the poly(dicarbazole) films was easily performed by immersion in an enzymatic aqueous solution. The amperometric response of the resulting biosensors to glucose has been studied at 0.6 V vs. aqueous saturated calomel electrode.

AB - New chiral dicarbazole derivatives functionalized by N-hydroxysuccinimide and pentafluorophenoxy groups have been synthesized and electrochemically characterized. Upon oxidative electropolymerization of these monomers in organic electrolytes electroactive poly(dicarbazole) films were formed on platimim electrodes. The subsequent chemical grafting of glucose oxidase on the poly(dicarbazole) films was easily performed by immersion in an enzymatic aqueous solution. The amperometric response of the resulting biosensors to glucose has been studied at 0.6 V vs. aqueous saturated calomel electrode.

KW - Biosensor

KW - Carbazole

KW - Chiral polymer

KW - Electropolymerization

KW - Glucose oxidase

UR - http://www.scopus.com/inward/record.url?scp=0033659914&partnerID=8YFLogxK

U2 - 10.1002/1521-4109(200010)12:14<1107::AID-ELAN1107>3.0.CO;2-8

DO - 10.1002/1521-4109(200010)12:14<1107::AID-ELAN1107>3.0.CO;2-8

M3 - Article

AN - SCOPUS:0033659914

SN - 1040-0397

VL - 12

SP - 1107

EP - 1112

JO - Electroanalysis

JF - Electroanalysis

IS - 14

ER -

Electrogenerated poly(chiral dicarbazole) films for the reagentless grafting of enzymes

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this