Engineering large perpendicular magnetic anisotropy in amorphous ferrimagnetic gadolinium cobalt alloys

Amorphous magnetic alloys with large perpendicular magnetic anisotropy (PMA) have emerged as a suitable material choice for spintronic memory and high-frequency non-reciprocal devices on-chip. Unlike ferromagnets, ferrimagnets offer faster switching dynamics, lower net saturation magnetization, minimal stray field and a lower net angular momentum. Ferrimagnetic thin films of Gd_xCo_1−x sputter deposited as heterostructures of Ta/Pt/Gd_xCo_1−x(t)/Pt on Si/SiO₂ have bulk-like PMA for thicknesses of 5-12 nm and room-temperature magnetic compensation for x = 28-32%. Preferential oxygenation of GdCo has been found to increase the effective anisotropy energy density by an order of magnitude and produce near-ideal remanence ratios. X-ray photoelectron spectroscopy accurately quantifies the metal-oxidation ratio, which shows that an oxygen-rich and Co-deficient stoichiometry (Gd₂₁Co₂₈O₅₁) likely weakens the ferromagnetic exchange interaction between Co-Co and contributes additional antiferromagnetic exchange through superexchange-like interactions between Gd and Co via O, resulting in a stronger out-of-plane magnetization. Even greater PMA and giant-anisotropy field of 11 kOe are achieved in super-lattices of the Gd₂₁Co₂₈O₅₁ heterostructure. The combination of ferrimagnetic ordering in amorphous Gd_xCo_1−x and its affordance of pathways for engineering large PMA will enable the design of integrated high-frequency devices beyond 30 GHz and ultrafast energy efficient memory devices with switching speeds down to tens of picoseconds.