Gas phase spectroscopy of the pentapeptide FDASV

  • Ali Abo-Riziq
  • , John E. Bushnell
  • , Bridgit Crews
  • , Michael Callahan
  • , Louis Grace
  • , Mattanjah S. de Vries

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

IR-UV double resonance spectroscopy of the laser-desorbed, jet-cooled pentapeptide FDASV shows only one type of conformer in the gas phase. Comparison with computations at the B3LYP/6-31G** level suggests formation of an α-turn in the absence of solvent stabilization.

Original languageEnglish
Pages (from-to)227-230
Number of pages4
JournalChemical Physics Letters
Volume431
Issue number4-6
DOIs
StatePublished - 24 Nov 2006

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