High Temperature Martensitic Transformation and Giant Magnetocaloric Effect in Ni40Co10Mn41Sn9 Melt-Spun Ribbons

F. Chen; J. L. Sánchez Llamazares; C. F. Sánchez-Valdés; P. Müllner; Y. G. Shi; Y. X. Tong; L. Li

doi:10.1016/j.jallcom.2018.02.091

High Temperature Martensitic Transformation and Giant Magnetocaloric Effect in Ni₄₀Co₁₀Mn₄₁Sn₉ Melt-Spun Ribbons

F. Chen, J. L. Sánchez Llamazares, C. F. Sánchez-Valdés, P. Müllner, Y. G. Shi, Y. X. Tong, L. Li

Micron School of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

We report a large magnetic entropy change associated with a high-temperature martensitic transformation in Ni₄₀Co₁₀Mn₄₁Sn₉ (at. %) melt-spun ribbons. The ribbons underwent a first-order forward martensitic transition and a reverse structural transition from the paramagnetic six-layered modulated martensite to a ferromagnetic austenite in the temperature range of 395–380 K. For a magnetic field change of 5 T (2 T), extremely large magnetic entropy changes of 33.9 (25) J kg⁻¹ K⁻¹ and 53 (22) J kg⁻¹ K⁻¹ upon reverse and forward martensitic transformations occurred. These values are among the largest for Ni-Mn based Heusler alloys reported so far. As compared with the large values upon heating, hysteresis losses upon cooling were negligibly low (only 0.36 J kg⁻¹). The present findings open up the possibility of elevated temperature magnetic cooling.

Original language	American English
Pages (from-to)	493-501
Number of pages	9
Journal	Journal of Alloys and Compounds
Volume	744
DOIs	https://doi.org/10.1016/j.jallcom.2018.02.091
State	Published - 5 May 2018

Keywords

Ni-Co-Mn-Sn
melt spinning
giant magnetic entropy change
high-temperature martensitic transformation
magnetic hysteresis loss

EGS Disciplines

Materials Science and Engineering

Access to Document

10.1016/j.jallcom.2018.02.091

Cite this

@article{f13f4e1fbae0421b9110716e7557eeab,

title = "High Temperature Martensitic Transformation and Giant Magnetocaloric Effect in Ni40Co10Mn41Sn9 Melt-Spun Ribbons",

abstract = "We report a large magnetic entropy change associated with a high-temperature martensitic transformation in Ni40Co10Mn41Sn9 (at. %) melt-spun ribbons. The ribbons underwent a first-order forward martensitic transition and a reverse structural transition from the paramagnetic six-layered modulated martensite to a ferromagnetic austenite in the temperature range of 395–380 K. For a magnetic field change of 5 T (2 T), extremely large magnetic entropy changes of 33.9 (25) J kg−1 K−1 and 53 (22) J kg−1 K−1 upon reverse and forward martensitic transformations occurred. These values are among the largest for Ni-Mn based Heusler alloys reported so far. As compared with the large values upon heating, hysteresis losses upon cooling were negligibly low (only 0.36 J kg−1). The present findings open up the possibility of elevated temperature magnetic cooling.",

keywords = "Ni-Co-Mn-Sn, melt spinning, giant magnetic entropy change, high-temperature martensitic transformation, magnetic hysteresis loss",

author = "F. Chen and {S{\'a}nchez Llamazares}, {J. L.} and S{\'a}nchez-Vald{\'e}s, {C. F.} and P. M{\"u}llner and Shi, {Y. G.} and Tong, {Y. X.} and L. Li",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2018",

month = may,

day = "5",

doi = "10.1016/j.jallcom.2018.02.091",

language = "American English",

volume = "744",

pages = "493--501",

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T1 - High Temperature Martensitic Transformation and Giant Magnetocaloric Effect in Ni40Co10Mn41Sn9 Melt-Spun Ribbons

AU - Chen, F.

AU - Sánchez Llamazares, J. L.

AU - Sánchez-Valdés, C. F.

AU - Müllner, P.

AU - Shi, Y. G.

AU - Tong, Y. X.

AU - Li, L.

PY - 2018/5/5

Y1 - 2018/5/5

N2 - We report a large magnetic entropy change associated with a high-temperature martensitic transformation in Ni40Co10Mn41Sn9 (at. %) melt-spun ribbons. The ribbons underwent a first-order forward martensitic transition and a reverse structural transition from the paramagnetic six-layered modulated martensite to a ferromagnetic austenite in the temperature range of 395–380 K. For a magnetic field change of 5 T (2 T), extremely large magnetic entropy changes of 33.9 (25) J kg−1 K−1 and 53 (22) J kg−1 K−1 upon reverse and forward martensitic transformations occurred. These values are among the largest for Ni-Mn based Heusler alloys reported so far. As compared with the large values upon heating, hysteresis losses upon cooling were negligibly low (only 0.36 J kg−1). The present findings open up the possibility of elevated temperature magnetic cooling.

AB - We report a large magnetic entropy change associated with a high-temperature martensitic transformation in Ni40Co10Mn41Sn9 (at. %) melt-spun ribbons. The ribbons underwent a first-order forward martensitic transition and a reverse structural transition from the paramagnetic six-layered modulated martensite to a ferromagnetic austenite in the temperature range of 395–380 K. For a magnetic field change of 5 T (2 T), extremely large magnetic entropy changes of 33.9 (25) J kg−1 K−1 and 53 (22) J kg−1 K−1 upon reverse and forward martensitic transformations occurred. These values are among the largest for Ni-Mn based Heusler alloys reported so far. As compared with the large values upon heating, hysteresis losses upon cooling were negligibly low (only 0.36 J kg−1). The present findings open up the possibility of elevated temperature magnetic cooling.

KW - Ni-Co-Mn-Sn

KW - melt spinning

KW - giant magnetic entropy change

KW - high-temperature martensitic transformation

KW - magnetic hysteresis loss

UR - http://www.scopus.com/inward/record.url?scp=85042013696&partnerID=8YFLogxK

UR - https://scholarworks.boisestate.edu/mse_facpubs/331

U2 - 10.1016/j.jallcom.2018.02.091

DO - 10.1016/j.jallcom.2018.02.091

M3 - Article

SN - 0925-8388

VL - 744

SP - 493

EP - 501

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -