Structural Stability and Microwave Dielectric Properties of (1-x)Ba(Mg1/2W1/2)O3−xBa(RE2/3W1/3)O3 (RE = Sm, Dy, Y, Yb) Solid Solutions

Jianjiang Bian; Jiayin Wu; Rick Ubic; C. Karthik; Y. Wu

doi:10.1016/j.jeurceramsoc.2014.11.015

Structural Stability and Microwave Dielectric Properties of (1-x)Ba(Mg_1/2W_1/2)O_3−xBa(RE_2/3W_1/3)O₃ (RE = Sm, Dy, Y, Yb) Solid Solutions

Jianjiang Bian, Jiayin Wu, Rick Ubic, C. Karthik, Y. Wu

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The structural stability and microstructure of (1-x)Ba(Mg_1/2W_1/2)O_3-xBa(RE_2/3W_1/3)O₃ (RE=Sm, Dy, Y, Yb) ceramics have been investigated by X-ray diffraction (XRD), Raman spectrometry, transmission electron microscopy (TEM) and scanning electron microscopy (SEM) in this work. Microwave dielectric properties were studied in the frequency range 7-13GHz. Phase-pure solid solutions formed in space group Fm-3m within the compositional range of x=0.01-0.05. The local ordering of the two cations (RE³⁺ and W⁶⁺or Mg²⁺) produced an internal lattice-induced strain and charge-imbalance clusters which greatly affected the structural stability and Q×f value.

Original language	American English
Pages (from-to)	1431-1439
Number of pages	9
Journal	Journal of the European Ceramic Society
Volume	35
Issue number	5
DOIs	https://doi.org/10.1016/j.jeurceramsoc.2014.11.015
State	Published - 1 May 2015

Keywords

double perovskite
microwave dielectric properties
structural stability
short-range ordering

EGS Disciplines

Materials Science and Engineering

Access to Document

10.1016/j.jeurceramsoc.2014.11.015

https://doi.org/10.1016/j.jeurceramsoc.2014.11.015

Cite this

@article{30751af77f1243dc92f4f624f9c350a5,

title = "Structural Stability and Microwave Dielectric Properties of (1-x)Ba(Mg1/2W1/2)O3−xBa(RE2/3W1/3)O3 (RE = Sm, Dy, Y, Yb) Solid Solutions",

abstract = "The structural stability and microstructure of (1-x)Ba(Mg1/2W1/2)O3-xBa(RE2/3W1/3)O3 (RE=Sm, Dy, Y, Yb) ceramics have been investigated by X-ray diffraction (XRD), Raman spectrometry, transmission electron microscopy (TEM) and scanning electron microscopy (SEM) in this work. Microwave dielectric properties were studied in the frequency range 7-13GHz. Phase-pure solid solutions formed in space group Fm-3m within the compositional range of x=0.01-0.05. The local ordering of the two cations (RE3+ and W6+or Mg2+) produced an internal lattice-induced strain and charge-imbalance clusters which greatly affected the structural stability and Q×f value.",

keywords = "double perovskite, microwave dielectric properties, structural stability, short-range ordering",

author = "Jianjiang Bian and Jiayin Wu and Rick Ubic and C. Karthik and Y. Wu",

note = "Publisher Copyright: {\textcopyright} 2014 Elsevier Ltd.",

year = "2015",

month = may,

day = "1",

doi = "10.1016/j.jeurceramsoc.2014.11.015",

language = "American English",

volume = "35",

pages = "1431--1439",

number = "5",

}

TY - JOUR

T1 - Structural Stability and Microwave Dielectric Properties of (1-x)Ba(Mg1/2W1/2)O3−xBa(RE2/3W1/3)O3 (RE = Sm, Dy, Y, Yb) Solid Solutions

AU - Bian, Jianjiang

AU - Wu, Jiayin

AU - Ubic, Rick

AU - Karthik, C.

AU - Wu, Y.

PY - 2015/5/1

Y1 - 2015/5/1

N2 - The structural stability and microstructure of (1-x)Ba(Mg1/2W1/2)O3-xBa(RE2/3W1/3)O3 (RE=Sm, Dy, Y, Yb) ceramics have been investigated by X-ray diffraction (XRD), Raman spectrometry, transmission electron microscopy (TEM) and scanning electron microscopy (SEM) in this work. Microwave dielectric properties were studied in the frequency range 7-13GHz. Phase-pure solid solutions formed in space group Fm-3m within the compositional range of x=0.01-0.05. The local ordering of the two cations (RE3+ and W6+or Mg2+) produced an internal lattice-induced strain and charge-imbalance clusters which greatly affected the structural stability and Q×f value.

AB - The structural stability and microstructure of (1-x)Ba(Mg1/2W1/2)O3-xBa(RE2/3W1/3)O3 (RE=Sm, Dy, Y, Yb) ceramics have been investigated by X-ray diffraction (XRD), Raman spectrometry, transmission electron microscopy (TEM) and scanning electron microscopy (SEM) in this work. Microwave dielectric properties were studied in the frequency range 7-13GHz. Phase-pure solid solutions formed in space group Fm-3m within the compositional range of x=0.01-0.05. The local ordering of the two cations (RE3+ and W6+or Mg2+) produced an internal lattice-induced strain and charge-imbalance clusters which greatly affected the structural stability and Q×f value.

KW - double perovskite

KW - microwave dielectric properties

KW - structural stability

KW - short-range ordering

UR - https://scholarworks.boisestate.edu/mse_facpubs/216

UR - https://doi.org/10.1016/j.jeurceramsoc.2014.11.015

U2 - 10.1016/j.jeurceramsoc.2014.11.015

DO - 10.1016/j.jeurceramsoc.2014.11.015

M3 - Article

SN - 0955-2219

VL - 35

SP - 1431

EP - 1439

JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

IS - 5

ER -