Synthesis of Chalcogenide Glasses

Bryan Wright, Maria Mitkova

Research output: Contribution to conferencePoster

Abstract

Semiconducting chalcogenide glasses are fascinating materials with important applications in phase-change memory, nanoionic memristive memory, radiation sensing, gas sensing, optical storage, and microfluidics.

Chalcogenide glasses contain sulfur, selenium and/or tellurium. Combined with a variety of other elements, these three chalcogens form a large family of semiconducting glasses with band gaps ranging from 1 to 3 eV.

Synthesizing chalcogenide glasses is a delicate process. Measurements and mixing of elements is done at very precise levels. The chalcogenide compounds are reacted in vacuum-sealed fused-silica ampoules at temperatures approaching 1000⁰C for several days. The final step of the process is fast quenching in a liquid coolant in order to preserve the amorphous state.

In this work we describe the synthesis of several binary chalcogenide glasses from the systems Ge-Se and Ge-S. Temperature regimes are presented and discussed within the context of system specific phase diagrams. Images of synthesized glasses are presented and the correlation between appearance, composition and structure are discussed.

Original languageAmerican English
StatePublished - 16 Apr 2012
Event2012 Undergraduate Research and Scholarship Conference - Boise State University, Boise, United States
Duration: 16 Apr 2012 → …
https://scholarworks.boisestate.edu/2012_under_conf/

Conference

Conference2012 Undergraduate Research and Scholarship Conference
Abbreviated title2012 URS
Country/TerritoryUnited States
CityBoise
Period16/04/12 → …
Internet address

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