The Effect of A-Site Vacancies on Cell Volume and Tolerance Factor of Perovskites

Rick Ubic; Kevin Tolman; Kokfoong Chan; Nicole Lundy; Steven Letourneau; Waltraud Kriven

doi:10.1002/9781118744109.ch36

The Effect of A-Site Vacancies on Cell Volume and Tolerance Factor of Perovskites

Rick Ubic
, Kevin Tolman
, Kokfoong Chan
, Nicole Lundy
, Steven Letourneau
, Waltraud Kriven

Micron School of Materials Science and Engineering

Boise State University
University of Illinois at Urbana-Champaign

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

3 Scopus citations

Abstract

Point defects like vacancies can have a profound effect on the structure of perovskite ceramics, but the exact mechanisms by which they do this are unclear. A predictive model for the pseudocubic lattice constant of perovskites, based solely on published ionic radii data, has been developed and adapted as a model for tolerance factor. These models more consistently predict both pseudocubic lattice constant, hence cell volume, and the tolerance factor than existing methods, thus also more accurately modeling the temperature coefficient of resonant frequency (TCF). The relationship between tolerance factor and TCF is revisited.

Original language	American English
Title of host publication	Processing and Properties of Advanced Ceramics and Composites V
Subtitle of host publication	Ceramic Transactions
Pages	331-336
Number of pages	6
Volume	240
ISBN (Electronic)	9781118744109
DOIs	https://doi.org/10.1002/9781118744109.ch36
State	Published - 2013
Event	Processing and Properties of Advanced Ceramics and Composites V - Materials Science and Technology 2012 Conference, MS and T 2012 - Pittsburgh, PA, United States Duration: 7 Oct 2012 → 12 Oct 2012

Publication series

Name	Ceramic Transactions
Volume	240
ISSN (Print)	1042-1122

Conference

Conference	Processing and Properties of Advanced Ceramics and Composites V - Materials Science and Technology 2012 Conference, MS and T 2012
Country/Territory	United States
City	Pittsburgh, PA
Period	7/10/12 → 12/10/12

Keywords

perovskites
pseudocubic lattice constant
electroceramics
superconductors
microwave applications

EGS Disciplines

Materials Science and Engineering

Access to Document

10.1002/9781118744109.ch36

Cite this

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title = "The Effect of A-Site Vacancies on Cell Volume and Tolerance Factor of Perovskites",

abstract = "Point defects like vacancies can have a profound effect on the structure of perovskite ceramics, but the exact mechanisms by which they do this are unclear. A predictive model for the pseudocubic lattice constant of perovskites, based solely on published ionic radii data, has been developed and adapted as a model for tolerance factor. These models more consistently predict both pseudocubic lattice constant, hence cell volume, and the tolerance factor than existing methods, thus also more accurately modeling the temperature coefficient of resonant frequency (TCF). The relationship between tolerance factor and TCF is revisited.",

keywords = "perovskites, pseudocubic lattice constant, electroceramics, superconductors, microwave applications",

author = "Rick Ubic and Kevin Tolman and Kokfoong Chan and Nicole Lundy and Steven Letourneau and Waltraud Kriven",

note = "Publisher Copyright: {\textcopyright} 2013 The American Ceramic Society. All rights reserved.; Processing and Properties of Advanced Ceramics and Composites V - Materials Science and Technology 2012 Conference, MS and T 2012 ; Conference date: 07-10-2012 Through 12-10-2012",

year = "2013",

doi = "10.1002/9781118744109.ch36",

language = "American English",

isbn = "9781118744093",

volume = "240",

series = "Ceramic Transactions",

pages = "331--336",

booktitle = "Processing and Properties of Advanced Ceramics and Composites V",

}

Ubic, R, Tolman, K, Chan, K, Lundy, N, Letourneau, S & Kriven, W 2013, The Effect of A-Site Vacancies on Cell Volume and Tolerance Factor of Perovskites. in Processing and Properties of Advanced Ceramics and Composites V: Ceramic Transactions. vol. 240, Ceramic Transactions, vol. 240, pp. 331-336, Processing and Properties of Advanced Ceramics and Composites V - Materials Science and Technology 2012 Conference, MS and T 2012, Pittsburgh, PA, United States, 7/10/12. https://doi.org/10.1002/9781118744109.ch36

The Effect of A-Site Vacancies on Cell Volume and Tolerance Factor of Perovskites. / Ubic, Rick; Tolman, Kevin; Chan, Kokfoong et al.
Processing and Properties of Advanced Ceramics and Composites V: Ceramic Transactions. Vol. 240 2013. p. 331-336 (Ceramic Transactions; Vol. 240).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - The Effect of A-Site Vacancies on Cell Volume and Tolerance Factor of Perovskites

AU - Ubic, Rick

AU - Tolman, Kevin

AU - Chan, Kokfoong

AU - Lundy, Nicole

AU - Letourneau, Steven

AU - Kriven, Waltraud

PY - 2013

Y1 - 2013

N2 - Point defects like vacancies can have a profound effect on the structure of perovskite ceramics, but the exact mechanisms by which they do this are unclear. A predictive model for the pseudocubic lattice constant of perovskites, based solely on published ionic radii data, has been developed and adapted as a model for tolerance factor. These models more consistently predict both pseudocubic lattice constant, hence cell volume, and the tolerance factor than existing methods, thus also more accurately modeling the temperature coefficient of resonant frequency (TCF). The relationship between tolerance factor and TCF is revisited.

AB - Point defects like vacancies can have a profound effect on the structure of perovskite ceramics, but the exact mechanisms by which they do this are unclear. A predictive model for the pseudocubic lattice constant of perovskites, based solely on published ionic radii data, has been developed and adapted as a model for tolerance factor. These models more consistently predict both pseudocubic lattice constant, hence cell volume, and the tolerance factor than existing methods, thus also more accurately modeling the temperature coefficient of resonant frequency (TCF). The relationship between tolerance factor and TCF is revisited.

KW - perovskites

KW - pseudocubic lattice constant

KW - electroceramics

KW - superconductors

KW - microwave applications

UR - https://www.scopus.com/pages/publications/84880887141

UR - https://scholarworks.boisestate.edu/mse_facpubs/163

U2 - 10.1002/9781118744109.ch36

DO - 10.1002/9781118744109.ch36

M3 - Conference contribution

SN - 9781118744093

VL - 240

T3 - Ceramic Transactions

SP - 331

EP - 336

BT - Processing and Properties of Advanced Ceramics and Composites V

T2 - Processing and Properties of Advanced Ceramics and Composites V - Materials Science and Technology 2012 Conference, MS and T 2012

Y2 - 7 October 2012 through 12 October 2012

ER -

The Effect of A-Site Vacancies on Cell Volume and Tolerance Factor of Perovskites

Abstract

Publication series

Conference

Keywords

EGS Disciplines

Access to Document

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Cite this