Thermodynamics and statistical mechanics of material transport in non-isothermal colloid systems

Semen Semenov, Martin Schimpf

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

1 Scopus citations

Abstract

This chapter outlines a microscopic approach to the theory of material transport in colloid systems. Initially, the approach is applied to colloidal particles suspended in binary one-phase liquid mixtures. Next, the approach is extended to the onset of phase layering in these systems. Finally, we extend the approach to dilute ternary systems with the possibility for manipulating particles of the dilute component in a temperature gradient. In our discussions we analyze the current state of thermodynamic theory, identifying refinements that are critical to applying non-equilibrium thermodynamics and statistical mechanics to material transport in non-isothermal mixtures.

Original languageEnglish
Title of host publicationColloids
Subtitle of host publicationClassification, Properties and Applications
Pages145-199
Number of pages55
StatePublished - Nov 2012

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