Thermodynamics of Mass Transport in Diluted Suspensions of Charged Particles in Non-Isothermal Liquid Electrolytes

Semen N. Semenov, Martin Schimpf

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

A thermodynamic theory is developed for the thermophoresis of dilute suspensions of charged colloid particles in electrolyte solutions. The calculation of relevant thermodynamic parameters using statistical mechanics is carried out in the Debye–Hueckel approximation. The main experimental features observed for such systems are explained.

Original languageAmerican English
Pages (from-to)280-286
Number of pages7
JournalComptes Rendus Mécanique
Volume339
Issue number5
DOIs
StatePublished - 1 May 2011

Keywords

  • colloid particles
  • electrolyte solution
  • non-equilibrium thermodynamics
  • thermodiffusion

EGS Disciplines

  • Chemistry

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