Abstract
Vibrational lifetimes and absorption spectra of the asymmetric CO stretching mode (∼1990 cm-1) of W(CO)6 in supercritical CO2 are reported as functions of solvent density and temperature. Close to the critical temperature, the observables are density independent over a twofold range of density. Possible explanations are discussed for this unique behavior.
Original language | English |
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Pages (from-to) | 8973-8976 |
Number of pages | 4 |
Journal | Journal of Chemical Physics |
Volume | 105 |
Issue number | 19 |
DOIs | |
State | Published - 1996 |
Externally published | Yes |